Liquid hydrogen (LH2) is typically stored in cylindrical tanks. Spherical tanks can carry a significant amount of liquid. Cryogenic tanks are vacuum insulated to minimize evaporation losses and contain redundant pressure release mechanisms to prevent over-pressurization. Liquid hydrogen tanks typically operate at pressures of up to 850 kPa (123 psi).
The pressure release system will function at a maximum pressure of 1,035 kPa (150 psi) in most tanks. Even if hydrogen is not drawn from the tank, LH2 evaporation will occur, and the resulting pressure will be released on a regular basis by the pressure relief mechanism as part of normal operation.
Cryogenic tanks are constructed and manufactured in accordance with well-established norms such as:
- The US Department of Transportation’s restrictions apply to transportable storage tanks.
- Transport Canada imposes limitations on mobile storage tanks.
- Regulations such as the ASME Boiler and Pressure Vessel Code (BPVC) apply to stationary storage tanks.
- Larger tanks are occasionally designed in line with standards such as API Standard 620, Design and Construction of Large, Welded, Low-Pressure Storage Tanks.
- Stationary tank supports should be able to resist fire exposure without failing.
The paperwork for each vessel should include a description of the vessel, a list of available drawings or other materials, the most recent inspection results, and the name of the responsible person. Vessels must also be marked in accordance with the applicable regulations. Each cryogenic liquid storage tank (stationary and mobile) should be legibly labeled “LIQUEFIED HYDROGEN – FLAMMABLE GAS.”
A warning labeled “Do not spray water on or into the vent hole” should be displayed on the vessel near the pressure-relief valve vent stack. Local first responders and firefighters should be specially trained in LH2 spill response tactics.
Cryogenic liquids and the containers in which they are stored
Cryogenic tanks are used to safeguard cryogenic liquids. Cryogenic liquids are liquefied gases that have temperatures of -150 °C or below. Byproducts include oxygen, argon, nitrogen, hydrogen, and helium. Cryogenic tanks may also be used to store gases at higher temperatures, such as LNG, carbon dioxide, and nitrous oxide. These are components of gas supply systems used in a number of sectors including metal processing, medical technology, electronics, water treatment, energy generation, and food processing. Low temperature chilling uses using cryogenic liquids include engineering shrink fitting, food freezing, and bio-sample storage.
Cryogenic tanks are thermally insulated and are typically equipped with a vacuum jacket. They are created and manufactured to stringent standards in compliance with international design criteria. They might be fixed, movable, or transportable.
Static cryogenic tanks are designed for permanent usage; however, transportable small tanks on wheels for use in workshops and laboratories are provided. Because static cryogenic tanks are typically classified as pressure vessels, new tanks and their associated systems will be built and installed in accordance with the Pressure Equipment (Safety) Regulations. For applications requiring direct access to the liquid, non-pressurized open neck vessels (Dewar flasks) are also available. The tanks are available in a range of sizes, pressures, and flow rates to meet the different demands of the customers. Tanks used to transport cryogenic liquids must comply with the Regulations on the Carriage of Dangerous Goods and the Use of Transportable Pressure Equipment.
Use, operation, maintenance, and disposal of cryogenic tanks
All applicable regulations, such as the Pressure Systems Safety Regulations for static tanks and the Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations for transportable tanks, must be followed when operating and maintaining cryogenic tanks. Cryogenic tanks must be maintained and operated by trained personnel.
The Regulations require cryogenic tanks to be inspected on a regular basis, as well as routinely maintained and subjected to formal examinations on a periodic basis for static tanks. To ensure that the tank is in safe operating condition between official examination times, an inspection and maintenance program should be created. This will include a Written Plan of Examination, which will be created by a competent person(s), as well as periodic formal examinations conducted in accordance with the scheme.
Transportable tanks must be inspected and tested on a regular basis, which may only be done by an Inspection Body recognized by the National Competent Authority, Department for Transport, in the United Kingdom (DfT). The Vehicle Certification Agency (VCA) website provides information on Examination Bodies that have been assigned to execute various tasks relating to tank and/or pressure equipment inspection. All inspections, examinations, and tests are documented, and these documents must be kept for the duration of the tank’s life.
Cryogenic tank users and owners have legal obligations as well as a duty of care to ensure that their equipment is properly maintained and operated. The user must undertake routine safety inspections. Daily inspections must be carried out. A gas company will only fill a tank if it believes it is safe to do so. While in use, a small amount of icing and ice may be visible. Small levels of ice are not cause for concern, but the quantity of ice should be checked on a frequent basis. To minimize excessive ice collection, de-icing should be conducted if ice continues to accumulate.
Cryogenic tank repair and modification
Any repair or modification to a cryogenic tank should be performed only by a skilled repairer in accordance with the design codes to which it was constructed, while taking current regulations and legislation into account. Such repairs or adjustments must not affect the structural integrity or the operation of any protective systems. All repairs and adjustments must be documented, and the documentation must be kept for the rest of the tank’s life.
Cryogenic tank revalidation
Cryogenic tanks must be assessed on a regular basis to ensure that they are safe to use. The revalidation period, which shall not exceed 20 years, shall be determined by a Competent Person. Mobile tanks should be rented for a shorter period of time due to the nature of their function. When a tank is revalidated, a report is created that must be kept with the tank data for the life of the tank.
Security for Cryogenic Tanks
Liquid oxygen, liquid nitrogen, and liquid argon are examples of cryogenic liquids. Their respective boiling points are as follows:
- -297.3oF | -183oC • -320.4°F | -195.8°C
- Liquid Oxygen Nitrogen in liquid form
- -302.6°F (-185.9°C) Argon Liquid
- The sublimation point of liquid CO2 is -109.3°F | -78.5°C.
To prevent heat transfer and sustain very low temperatures, the storage vessel must be correctly constructed. The water capacity of commercially available liquid oxygen, liquid nitrogen, and liquid argon storage tanks ranges from 350 to 13,000 US gallons (1,325 to 49,210 liters). The storage tanks for Cryogenic Bulk Tanks may be vertical, spherical, or horizontal, depending on the location and consumption demands.
Cryogenic liquid storage tanks are made up of three major components:
• Vessel of Internal Pressure
A cryogenic vessel made of stainless steel or other materials with high strength when exposed to cryogenic temperatures.
• The Outer Vessel
A vessel made of carbon steel or stainless steel. Under normal operating conditions, this vessel maintains the insulation around the inner pressure vessel and can also maintain a vacuum around the inner vessel. Most of the time, the external vessel is not exposed to cryogenic temperatures.
The vacuum-sealed space between the inner and outer vessels, which is filled with several inches of insulating material. The vacuum and insulating material help to reduce heat transfer and, as a consequence, the boil-off of the liquid oxygen, liquid nitrogen, or liquid argon contained inside the vessel.
The inner vessel of a storage tank is typically designed to sustain a maximum allowed operating pressure of 250 psig (1724 kPa). Vessels may be designed for higher or lower working pressures, as well as for specific uses. The service pressure of the vessel may be adjusted.
Caution: Storage Facility Maintenance
Only authorized and competent individuals should maintain and operate the liquid oxygen, liquid nitrogen, or liquid argon storage facility and its components. Safety concerns should be disclosed as soon as feasible.
General Safety Rules for Liquid Oxygen, Liquid Nitrogen, and Liquid Argon
The following are the fundamental safe handling criteria for liquid oxygen, liquid nitrogen, and liquid argon:
- Liquid oxygen, liquid nitrogen, or liquid argon should not be kept in confined spaces or in areas with inadequate ventilation.
- Ensure that cryogenic liquids are only handled by people who have been taught on the material’s properties and proper handling methods.
- Ensure that any piping where cryogenic liquids may get trapped between two valves or receptacles has pressure relief valves routed to adequately constructed outputs.
- Smoking and sparking are not allowed near liquid oxygen equipment or tanks. When approaching liquid oxygen tanks with an open flame, proceed with care.
Manufacturing of Cryogenic Tanks
The cryogenic stationary tanks are designed for the long-term storage of cryogenic liquefied gases under high pressure. Inner vessels for chosen medium / high pressure variations are made of austenitic stainless steel and cold stretched. These tanks can carry LIN, LOX, LAR, LNG, CO2, and N2O and are available in vertical or horizontal layouts. Lifting lugs with stainless steel inlay, integrated shipping supports, and high-quality vacuum-perlite system insulation with molecular sieve adsorber have shown excellent performance and extended hold duration for vacuum-insulated double wall tanks, resulting in a lower life cycle cost. Vertical cryogenic stationary tanks with thermosyphons, which are suited for cylinder filling applications, may also be produced. As a consequence, the tanks provide consistent and efficient cylinder filling while lowering losses and pump maintenance costs.
Cryogenic liquids exist at very low temperatures, necessitating the need of specialized transport and storage equipment. Cryogenic liquids, contrary to popular belief, cannot be kept in a standard container. This would make handling them challenging, as well as presenting health and safety risks to anybody who come into contact with them. Cryogenic tanks are designed specifically for this purpose. They are built of durable materials that can withstand such low temperatures. Additional protections are also included into the equipment to avoid leaking.
Cryogenic tanks are available in a wide range of designs and sizes. Static tanks, sometimes known as fixed tanks, are used in permanent locations, such as a cryogenic processing factory. Static tanks may also be small mobile tanks mounted on wheels for use in labs and factories. These small cryogenic tanks are also known as pressure vessels. Other non-pressurized open neck containers known as Dewar flasks may be utilized when direct access to the cryogenic liquid is required.
Repairing cryogenic tanks is possible, but it is not something that just about everyone can do. Any repairs or modifications to such tanks should be carried out by a skilled repairer who adheres to the design requirements that the tank was constructed to. They must also be familiar with current laws and regulations. Any and all repairs or alterations must be documented in order for records to be kept for the rest of the tank’s operating life.
What is the function of cryogenic tanks in the cryogenic treatment process?
Cryogenic tanks are critical parts of the cryogenic treatment process. Without them, it would be difficult to transport and store cryogenic liquids. As a consequence, the cryogenic treatment method would be impossible without these tanks. Their use is not limited to the storage and transportation of cryogenic objects. These tanks are also essential in the deep cryogenic treatment procedure, which involves immersing metals and polymers in cryogenic liquids for up to 24 hours.
This is not possible with a standard tank, as previously indicated. There would be too many factors at play, sabotaging the treatment process. That is why cryogenic tanks are critical to the whole process. Deep cryogenic treatment cannot be carried out without them.
The situation of the industry today: cryogenic tanks
There is a lot of legislation that governs the use of cryogenic tanks in the workplace. They must be operated and maintained in conformity with all applicable laws and regulations. The cryogenic tanks may only be maintained and handled by authorised certified persons. The industry abides by these guidelines. As a consequence, static tanks are inspected on a regular basis. In addition, routine maintenance and official exams are carried out.
The maintenance and inspection plan must be devised in order to ensure that the tank can operate safely at all times in between official tests. Transportable tanks must also be examined and tested on a regular basis, which only an inspection agency can perform. These inspections and tests must be documented, and the documentation must be retained for the life of the tank. The industry has a duty of care to maintain while owning or utilizing cryogenic tanks. Responsible gas suppliers will only fill a cryogenic tank if they are certain that it is safe to do so.
Major cryogenic tank manufacturers
Lapesa is a well-known manufacturer of pressure vessels. This family-owned company began in 1964 and manufactures cryogenic gas storage tanks, liquid fuel storage tanks, and other items. Zaragoza, Spain, is where the company’s production facilities are located. Its cryogenic tanks consist of two vessels, one within the other, with thermal insulation between them. The heat insulation is made up of an insulating material as well as a high vacuum that fills the space between the two vessels. The absorbent material increases vacuum stability. Lapesa manufactures cryogenic tanks with operational pressures ranging from 5 to 42 bar. They have been approved in compliance with the European Pressurised Equipment Directive 2014/68/EU.
• Linde Engineering, Inc.
Since 1960, Linde Engineering has provided cryogenic tanks for liquefied gases. It has supplied over 20,000 cryogenic tanks of the highest quality standard designs, as well as customised solutions tailored to the demands of the customer. Linde’s cryogenic tanks range in capacity from 3,000 to > 100,000 liters and have regular operating pressures of 18, 22, or 36 bar. They also comply with the European Pressure Equipment Directive. Each tank is vacuum insulated, and the interior vessels and tubing are made of stainless steel. For efficient insulation, the outside shell is properly coated, and a vacuum-perlite system with a molecular sieve adsorbent is employed.
Cryolor, an Air Liquide business, specializes in the manufacture of cryogenic tank solutions for the transportation of liquid nitrogen, argon, or oxygen. Its Claire 3 trailers have the highest payload of any stainless-steel trailer in their category, as well as the most stable and optimal space occupancy. Cryolor’s semi-trailers meet all key regulatory criteria, from the control console through the chassis and axles. It also makes swap-body/chassis tankers, iso-containers, and other products. Air Liquide has decades of experience in the development of cryogenic storage and transport systems. It is a market leader in its field.
• Auguste Auguste’s Cryogenics Cryogenics offers small and bulk cryogenic tanks for a range of applications. These tanks come in sizes ranging from 2,000 to 350,000 litres, with each vessel custom-built to the customer’s requirements. For optimal thermal performance, superior vacuum technology is employed in the company’s tanks, and all piping is composed of stainless steel for strength and corrosion resistance. These vacuum-insulated pressure containers hold cryogenic liquefied gases such as nitrogen, hydrogen, oxygen, carbon dioxide, and others. The company’s production factory is located in Slovakia and is ISO:9001 certified, as well as compliant with the European Pressure Equipment Directive 2014/68/EU.
Cryofab, Inc. is a market leader in cryogenic equipment as well. It manufactures and services cryogenic tanks and components, as well as supplying custom and standard fabrications to clients all over the globe. The company sells cryogenic tanks, double wall vacuum vessels, cold traps, pressure vessels, vacuum jacketed pipes, and other items. Its cryogenic tanks range in size from 1 litre to 5,000 litres and meet regulatory standards. Since its inception in 1971, Cryofab, Inc. has given solutions to clients in the semiconductor, laboratory, medical, industrial, and other sectors.
• Wessington Cryogenics
Wessington Cryogenics has been building cryogenic tanks since 1984. Its products have been certified in compliance with the major pressure vessel code requirements. Its cryogenic storage solutions range from open dewards for civilian use to military-grade liquid nitrogen, oxygen, and argon tanks. The company also sells spares and accessories, as well as entire automated liquid level management systems. Wessington Cryogenics also provides repair and refurbishment services, fixing all makes of cryogenic tanks and restoring them to “as new” state.